Researchers from the University of Bristol have found significant ongoing emissions of a potent ozone-depleting substance from eastern China.
The compound, carbon tetrachloride, contributes to the destruction of the Earth's ozone layer, which protects us from harmful ultraviolet radiation.
As a result, the production of carbon tetrachloride has been banned throughout the world since 2010 for uses that will result in its release to the atmosphere. However, recent studies have shown that global emissions have not declined as expected, with about 40,000 tonnes still being emitted each year.
The origin of these emissions has puzzled researchers for many years.
Alongside collaborators from South Korea, Switzerland, Australia, and the U.S., researchers at the University of Bristol aimed to quantify emissions from eastern Asia.
To do this, they used ground-based and airborne atmospheric concentration data from near the Korean peninsula and two models that simulate the transport of gases through the atmosphere.
Their results, published in the journal Geophysical Research Letters, show that around half of the 'missing' global emissions of carbon tetrachloride originated from eastern China between 2009 and 2016.
"Our results show that emissions of carbon tetrachloride from the eastern Asia region account for a large proportion of global emissions and are significantly larger than some previous studies have suggested," said Dr Mark Lunt, lead author of the study from the University of Bristol's School of Chemistry.
"Not only that, but despite the phase out of carbon tetrachloride production for emissive use in 2010, we found no evidence for a subsequent decrease in emissions."
In fact, emissions from certain regions may have increased slightly since 2010. The results from the study show the emergence of a new source of emissions from the Shandong province of China after 2012.
Whilst the results of this and earlier studies in Europe and the U.S. now explain a large part of the global distribution of carbon tetrachloride emissions, there are still large gaps in our knowledge. Furthermore, recent reports have suggested that very large amounts of this gas may be emitted inadvertently during the production of other chemicals such as chlorine.
"Our work shows the location of carbon tetrachloride emissions," said Dr Matt Rigby, Reader in Atmospheric Chemistry at the University of Bristol. "However, we don't yet know the processes or industries that are responsible. This is important because we don't know if it is being produced intentionally or inadvertently."
"There are areas of the world such as India, South America and other parts of Asia, where emissions of ozone-depleting gases may be ongoing, but detailed atmospheric measurements are lacking," he added.
It is hoped that this work can now be used by scientists and regulators to identify the cause of these emissions from eastern Asia. Ultimately, if these emissions can be avoided, it would hasten the recovery of the stratospheric ozone layer.
"Studies such as this show the importance of continued monitoring of ozone-depleting gases," Dr Lunt said. "There is a temptation to see ozone depletion as a problem that has been solved. But the monitoring of human-made ozone-depleting gases in the atmosphere is essential to ensure the continued success of the phase-out of these compounds."
(Source: University of Bristol)